Some stars spotted in Poundland, Rome? Daring! (9)
I believe the answer is:
andromeda
'some stars' is the definition.
(constellation)
'spotted in poundland rome? daring' is the wordplay.
'spotted in' indicates a hidden word.
'ANDROMEDA' is hidden within 'poundland rome daring'.
(Other definitions for andromeda that I've seen before include "Constellation; bog rosemary" , "Galaxy nearest ours" , "Adored man on constellation with great spiral nebula" , "Constellation; daughter of Cassiopeia" , "shrub" .)