Something afoot of an open nature (6)
I believe the answer is:
sandal
'something afoot' is the definition.
(whimsically, something worn on a foot)
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for sandal that I've seen before include "Light open-toed shoe" , "Item of footwear" , "Light open shoe" , "An open shoe for summer" , "One can go on foot" .)