Crossword Genius

Something toxic seen when peeling layers from lethal onion? (8)

Ross

I believe the answer is:

thallium

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'onion?' is the definition.
Although both the answer and definition are singular nouns, I cannot see how they can define each other.

I don't understand how the remainder of the clue works.

Can you help me to learn more?

(Other definitions for thallium that I've seen before include "Metallic element used in rat poison" , "Metallic element, Tl" .)

I've seen this clue in The Independent.
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