Sort of bed you'll get in the Thames valley (5)
I believe the answer is:
river
'valley' is the definition.
The answer and definition can be both natural objects as well as being singular nouns.
Maybe there's an association between them I don't understand?
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for river that I've seen before include "One splits" , "Natural flow of water" , "Flowing water" , "Tributary" , "flower" .)