Spanish line on mat for waltzer, did you say? (5)
I believe the answer is:
tilde
'spanish line' is the definition.
(accent mark used in Spanish)
I don't understand the remainder of the clue.
(Other definitions for tilde that I've seen before include "Spanish accent, as in se-or, ma-ana etc." , "Diacritical sign over letter" , "Diacritical mark over a letter thus, n" , "Augmentation of text" , "Spanish cedilla" .)