Spell out fully the thinking behind old money (7)
I believe the answer is:
expound
'spell out fully the thinking behind' is the definition.
'old money' is the wordplay.
'old' becomes 'ex'.
'money' becomes 'pound' (I've seen this before).
'ex'+'pound'='EXPOUND'
(Other definitions for expound that I've seen before include "Set forth, explain in detail" , "Elucidate" , "Spell out" , "Set out in a detailed and learned way" , "Elaborate" .)