Standard of behaviour head teacher announced (9)
I believe the answer is:
principle
'standard of behaviour' is the definition.
'head teacher announced' is the wordplay.
'head teacher' becomes 'principal' (synonyms).
'announced' shows a homophone (sound like).
'principal' sounds like 'PRINCIPLE'.
(Other definitions for principle that I've seen before include "Set of rules" , "Basic standard" , "Morally correct behaviour" , "In which, theoretically" , "Axiom" .)