Starfleet's Captain Douglas? (4)
I believe the answer is:
kirk
'captain douglas?' is the definition.
'kirk' can be an answer for 'captain' (I've seen this before). I'm not certain of the 'douglas?' bit.
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for kirk that I've seen before include "Church of Scotland" , "Star Trek captain - Scottish church" , "Presbyterian building?" , "Scots church" .)