Starring element? (4)
I believe the answer is:
lead
I believe this is a double definition.
'starring' is the first definition.
(as in a lead performer)
'element?' is the second definition.
(lead is a kind of element)
(Other definitions for lead that I've seen before include "guitar accessory?" , "Metal -- Pb" , "writing material" , "Actor playing the principal role" , "Be ahead of - guide" .)