Starting with PR this awful woman makes headway (6)
I believe the answer is:
ogress
'starting with pr this awful woman makes headway' is the definition.
The definition suggests a singular noun which matches the answer.
This is all the clue.
Can you help me to learn more?
(Other definitions for ogress that I've seen before include "Female giant in fairy tale" , "Female giant in fairytales" , "Scary female" , "Particular nasty woman" , "'bloody difficult woman' ... ?" .)