Stays as Cornish capital takes the place of another county's capital (6)
I believe the answer is:
corset
'stays' is the definition.
(stays can refer to a corset)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for corset that I've seen before include "A lady's old foundation garment" , "Female undergarment" , "Sector (anag)" , "Item of underwear" , "Restraining undergarment" .)