Steers vessels round one corner (6)
I believe the answer is:
pilots
'steers' is the definition.
(piloting is a kind of steering)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for pilots that I've seen before include "Fliers or guides" , "They are licensed to fly aircraft" , "People who guide ships going into or out of a harbour" , "Airmen" , "They steer ships in and out of harbours" .)