Stick at reflecting on heartache (6)
I believe the answer is:
attach
'stick' is the definition.
(I know that stick is a more specific form of the action fasten)
'at reflecting on heartache' is the wordplay.
'reflecting on heartache' becomes 'tach' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
'at'+'tach'='ATTACH'
Can you help me to learn more?
(Other definitions for attach that I've seen before include "Document carriers" , "Unite?" , "'Affix, fasten (6)'" , "Fix to something else" , "Join, connect" .)