Substitute book (7)
I believe the answer is:
reserve
This clue is a double definition.
'substitute' is the first definition.
('reserve' can be a synonym of 'substitute')
'book' is the second definition.
(I've seen this before)
(Other definitions for reserve that I've seen before include "Lack of openness" , "Secure" , "Keep back - book" , "Hold back" , "Set aside - shyness" .)