Substitute left over copper money (5)
I believe the answer is:
locum
'substitute' is the definition.
(locum is a kind of substitute)
'left over copper money' is the wordplay.
'left over' becomes 'lo' (this could be a standard abbreviation of which I'm unaware).
'copper' becomes 'cu' (chemical symbol).
'money' becomes 'm' (abbreviation in economics).
'lo'+'cu'+'m'='LOCUM'
Can you help me to learn more?
(Other definitions for locum that I've seen before include "Medical temp?" , "He fills in" , "Relief doctor" , "Professional temp" , "temporary occupant" .)