Such a sum, presumably, has no odd pence (4)
I believe the answer is:
tidy
'such' is the definition.
Both the definition and answer are adjectives. Perhaps there's a link between them I don't understand?
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for tidy that I've seen before include "Spruce up" , "Neat and orderly" , "Considerable (sum); neat" , "Arranged neatly" , "Spick-and-span" .)