Such a villain is clearly roguish (4)
I believe the answer is:
arch
'roguish' is the definition.
(I've seen this before)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for arch that I've seen before include "one under a foot?" , "(archaic)" , "Curve of a bridge" , "Clever" , "Teasing; part of foot" .)