Such blondes can be very sweet (5)
I believe the answer is:
honey
'sweet' is the definition.
(thesaurus)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for honey that I've seen before include "Made by bees from nectar" , "Food from hive" , "sweet thing" , "Sweet food" , "Sweet product of insects" .)