Superior sweets with a twist (4)
I believe the answer is:
smug
'superior' is the definition.
(I've seen this before)
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for smug that I've seen before include "Self-satisfied, stuffy" , "Overly complacent" , "Full of oneself" , "Self-satisfied and vain" , "irritating expression" .)