Surprise opening of games was irritating (5)
I believe the answer is:
stung
'irritating' is the definition.
Both the answer and definition are adjectives. Perhaps they are linked in a way I don't understand?
'surprise opening of games' is the wordplay.
'surprise' becomes 'stun' (stunning is a kind of surprising).
'opening of' indicates taking the first letters.
The first letter of 'games' is 'g'.
'stun'+'g'='STUNG'
'was' acts as a link.
Can you help me to learn more?
(Other definitions for stung that I've seen before include "Caused sharp pain" , "Bitten, by a bee say" , "cheated" , "like Ray did, perhaps" , "goaded" .)