Surprisingly he paints one treading the boards (8)
I believe the answer is:
thespian
'one treading the boards' is the definition.
The answer is a person as well as being a singular noun. This is suggested by the definition.
'surprisingly he paints' is the wordplay.
'surprisingly' is an anagram indicator (a surprising ordering of the letters).
'he'+'paints'='hepaints'
'hepaints' with letters rearranged gives 'THESPIAN'.
Can you help me to learn more?
(Other definitions for thespian that I've seen before include "Actor - neat hips (anag)" , "Theatrical performer" , "stage performer" , "Stage actor" , "A formal actor" .)