Suspect I can't - firstly, peeping Tom will probably like it (6)
I believe the answer is:
catnip
'tom will probably like it' is the definition.
I can't judge whether this definition defines the answer.
'suspect i can't firstly peeping' is the wordplay.
'suspect' indicates an anagram (a suspicious or unusual spelling).
'firstly' says to take the initial letters.
The initial letter of 'peeping' is 'p'.
'i'+'cant'='icant'
'icant' is an anagram of 'catni'.
'catni'+'p'='CATNIP'
Can you help me to learn more?
(Other definitions for catnip that I've seen before include "Tin cap (anag.)" , "treat for kitten" , "Feline attractor (I, not E)" , "Plant with scented leaves which felines like" , "Hairy aromatic perennial herb strongly attractive to some pets" .)