Take over from superintendent adopting scheme (8)
I believe the answer is:
supplant
'take over from' is the definition.
(I've seen this before)
'superintendent adopting scheme' is the wordplay.
'superintendent' becomes 'supt' (I can't explain this - if you can you should believe this answer much more).
'adopting' is an insertion indicator (inserted letters are taken on or adopted).
'scheme' becomes 'plan' (synonyms).
'supt' enclosing 'plan' is 'SUPPLANT'.
Can you help me to learn more?
(Other definitions for supplant that I've seen before include "Oust" , "take another's place" , "Supersede and replace" , "Displace" .)