Taoiseach scratches aches, a bit (4)
I believe the answer is:
iota
'bit' is the definition.
(I've seen this in another clue)
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for iota that I've seen before include "Greek equivalent of the letter I" , "Greek letter; tiny amount" , "Scintilla" , "'Very small amount, jot (4)'" , "letter from abroad" .)