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Taoiseach scratches aches, a bit (4)

Ross

I believe the answer is:

iota

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'bit' is the definition.
(I've seen this in another clue)

I don't understand how the rest of the clue works.

Can you help me to learn more?

(Other definitions for iota that I've seen before include "Greek equivalent of the letter I" , "Greek letter; tiny amount" , "Scintilla" , "'Very small amount, jot (4)'" , "letter from abroad" .)

I've seen this clue in the Irish Times (Crosaire) and The Irish Times.
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