Tedious working alfresco (7)
I believe the answer is:
outside
'alfresco' is the definition.
('outside' can be a synonym of 'alfresco')
'tedious working' is the wordplay.
'working' indicates an anagram.
'tedious' is an anagram of 'OUTSIDE'.
(Other definitions for outside that I've seen before include "External surface" , "Tedious (anag)" , "Where smokers now often must go" , "Without" , "having emerged from the tunnel?" .)