The cheek is tender (5)
I believe the answer is:
brass
'the cheek' is the definition.
(brass neck can mean cheek or insolence)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for brass that I've seen before include "Family of wind instruments" , "Alloy; money" , "Alloy of Cu and Zn" , "An alloy; part of orchestra" , "Impertinence" .)