The first sort of believer (6)
I believe the answer is:
theist
'sort of believer' is the definition.
'the first' is the wordplay.
'first' becomes 'ist'.
'the'+'ist'='THEIST'
(Other definitions for theist that I've seen before include "Religious type" , "Person who believes in the existence of a god" , "Believer in the existence fo a god" , "Believer in a creator god" , "Person in good faith" .)