The late diplomat Madeleine eschewed second-class. OK? (7)
I believe the answer is:
alright
'ok?' is the definition.
('alright' can be a synonym of 'ok')
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for alright that I've seen before include "Satisfactory or adequate" , "Fine; agreed" , "satisfactory for some of us" , "Okay" , "OK, as some would have it" .)