The lowest sort of people but always found at the top (4)
I believe the answer is:
scum
'the lowest' is the definition.
(I've seen this before)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for scum that I've seen before include "Floating dirt on surface" , "Impurities on surface of liquid, or rotten people" , "Impurities layer" , "Impurities that rise to surface of liquid" , "rabble" .)