Theirs is a service station (6)
I believe the answer is:
police
'station' is the definition.
(police station is a kind of station)
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for police that I've seen before include "Emergency service" , "Bobby" , "Crime fighters" , "Limbs of the law" , "9a 19d" .)