They were in Russia before Tass was created outright! (5)
I believe the answer is:
tsars
'they' is the definition.
Both the answer and definition are plural nouns.
Maybe there's an association between them I don't understand?
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for tsars that I've seen before include "Old Russian rulers" , "Russian emperors" , "Old Russia's rulers" , "Old monarchs" .)