They're worn in pairs (6)
I believe the answer is:
braces
'pairs' is the definition.
('brace' can be a synonym of 'pair')
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for braces that I've seen before include "Supports for men's trousers" , "straps to hold your trousers up" , "They hold up men's trousers" , "Tighten" , "Supports for teeth or trousers" .)