Thrice married orderly (4)
I believe the answer is:
trim
'orderly' is the definition.
(synonyms)
'thrice married' is the wordplay.
'thrice' becomes 'tri' (I am not sure about this - if you are sure you should believe this answer much more).
'married' becomes 'm'.
'tri'+'m'='TRIM'
Can you help me to learn more?
(Other definitions for trim that I've seen before include "Neat and tidy as a town in Meath" , "Cut off; slim and fit" , "Reduce slightly" , "Svelte" , "Prune or pare" .)