Time when one is out of work (7)
I believe the answer is:
leisure
I believe this is a double definition.
'time' is the first definition.
(I have seen 'Spare time' mean 'leisure' so perhaps 'time' could also mean 'leisure')
'one is out of work' is the second definition.
(thesaurus)
'when' acts as a link.
(Other definitions for leisure that I've seen before include "days off" , "Enjoyment of free time" , "Free time; relaxation" , "idle hours" , "Non-work activity" .)