TNT is explosive, so be very careful! (5)
I believe the answer is:
stint
'be very careful' is the definition.
I can't judge whether this definition defines the answer.
'tnt is explosive' is the wordplay.
'explosive' is an anagram indicator.
'tnt'+'is'='tntis'
'tntis' with letters rearranged gives 'STINT'.
'so' acts as a link.
Can you help me to learn more?
(Other definitions for stint that I've seen before include "Supply inadequately - fixed period of work" , "Allotted period (of work)" , "Spot of work" , "Stretch of work" , "Assignment" .)