To miss couplings is foolish of one who discusses the private lives of celebrities (6,9)
I believe the answer is:
gossip columnist
'one who discusses the private lives of celebrities' is the definition.
The answer is a person as well as being a singular noun. This is suggested by the definition.
'to miss couplings is foolish' is the wordplay.
'is foolish' is an anagram indicator (a foolish spelling).
'to'+'miss'+'couplings'='tomisscouplings'
'tomisscouplings' with letters rearranged gives 'GOSSIP COLUMNIST'.
'of' is the link.
Can you help me to learn more?
(Other definitions for gossip columnist that I've seen before include "Newspaper writer" , "journalist" .)