Toilet engaged? It looks serious (7)
I believe the answer is:
pofaced
'toilet engaged? it looks serious' is the definition.
I can't tell whether this definition defines the answer.
'toilet engaged?' is the wordplay.
'toilet' becomes 'po' (informal term for a chamber pot).
'engaged?' becomes 'faced' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
'po'+'faced'='POFACED'
Can you help me to learn more?
(Another definition for pofaced that I've seen is " visibly disapproving".)