Took a stimulant, being exhausted (4)
I believe the answer is:
used
This clue is a double definition.
'took a stimulant' is the first definition.
(used drugs)
'being exhausted' is the second definition.
(I've seen this before)
(Other definitions for used that I've seen before include "Put to a purpose" , "Brought into service" , "Sued (anag.)" , "Second-hand, not new" , "Exploited group" .)