Top headgear (5)
I believe the answer is:
crown
I believe this is a double definition.
'top' is the first definition.
(crown can mean the top of something)
'headgear' is the second definition.
(crown is a kind of headgear)
(Other definitions for crown that I've seen before include "Royal headdress" , "Old coin; whack on head" , "Monarch's headgear" , "Top of the head; coin" , "piece of tooth" .)