Totally clean? Not you, no way, Mr Johnson (7)
I believe the answer is:
premier
'johnson' is the definition.
(as in Boris Johnson, UK prime minister)
I can't explain the remainder of the clue.
(Other definitions for premier that I've seen before include "Foremost" , "First in importance" , "First - head of government" , "First (minister)" , "Earliest" .)