Tranquil, calm (6)
I believe the answer is:
serene
I believe this clue is a double definition.
'tranquil' is the first definition.
(synonyms)
'calm' is the second definition.
(synonyms)
(Other definitions for serene that I've seen before include "Calm and unruffled, like a princely title." , "Not agitated" , "Tranquil, perfectly calm" , "Calm, untroubled" , "Placid" .)