... transported, opening door firstly (9)
I believe the answer is:
entranced
'transported' is the definition.
(I've seen this before)
'opening door firstly' is the wordplay.
'opening' becomes 'entrance' (opening leading to a building).
'door firstly' becomes 'd' (I can't justify this - if you can you should give a lot more credence to this answer).
'entrance'+'d'='ENTRANCED'
Can you help me to learn more?
(Other definitions for entranced that I've seen before include ""Spellbound"?" , "Fascinated" , "Captivated" , "Filled with wonder" , "Delighted" .)