Twin-headed sorceress has a spasm (6)
I believe the answer is:
twitch
'a spasm' is the definition.
(I know that twitch is a type of spasm)
'twin-headed sorceress' is the wordplay.
'twin-headed' becomes 't' (this could be a standard abbreviation of which I'm unaware).
'sorceress' becomes 'witch' (synonyms).
't'+'witch'='TWITCH'
'has' is the link.
Can you help me to learn more?
(Other definitions for twitch that I've seen before include "pluck" , "Muscle spasm" , "Twinge" , "Sudden jerk" , "Move spasmodically" .)