Unaccompanied, but very much upset in this city (4)
I believe the answer is:
oslo
'this city' is the definition.
(capital of Norway)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for oslo that I've seen before include "Norway's capital city" , "Go solo to European capital" , "Nordic capital" , "Capital in throes of go-slow" , "Norwegian chief port" .)