Uncle Rods devious villain (9)
I believe the answer is:
scoundrel
'villain' is the definition.
('scoundrel' can be a synonym of 'villain')
'uncle rods devious' is the wordplay.
'devious' indicates anagramming the letters.
'uncle'+'rods'='unclerods'
'unclerods' with letters rearranged gives 'SCOUNDREL'.
(Other definitions for scoundrel that I've seen before include "Villain" , "Bounder" , "bad egg" , "Unprincipled rogue" , "Cad" .)