Underwear designed to inflame? No, to chill! (9)
I believe the answer is:
loincloth
'underwear designed' is the definition.
I can't judge whether this definition defines the answer.
'inflame? no to chill' is the wordplay.
'inflame?' indicates an anagram (I've seen 'inflamed' mean this).
'no'+'to'+'chill'='notochill'
'notochill' with letters rearranged gives 'LOINCLOTH'.
'to' acts as a link.
Can you help me to learn more?
(Other definitions for loincloth that I've seen before include "Sort of dhoti" , "Garment Indian may have" , "Minimum clothing?" , "Minimal garment" , "Simple garment" .)