Union Jack, maybe, on vessel (6)
I believe the answer is:
flagon
'vessel' is the definition.
(I know that flagon is a type of vessel)
'union jack maybe on' is the wordplay.
'union jack maybe' becomes 'flag' (the union jack is a flag).
'flag'+'on'='FLAGON'
(Other definitions for flagon that I've seen before include "Drinking vessel" , "Large rounded bottle, may contain cider" , "Large round bottle as for cider" , "Large wine vessel" , "Large drinks container" .)