Upset? Depends how big-headed one is (7)
I believe the answer is:
capsize
'upset?' is the definition.
(I've seen this before)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for capsize that I've seen before include "Upset" , "Turn so that keel faces upwards" , "Of boat, turn turtle" , "Overturn (a boat)" .)