Upstart in female attire backing sentry (5)
I believe the answer is:
guard
'sentry' is the definition.
(I've seen this before)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for guard that I've seen before include "Custodian" , "See 1" , "Yeomen" , "Protect(or)" , "Sentinel" .)