Urgent -- I'm to intercede (9)
I believe the answer is:
immediate
'urgent' is the definition.
(I've seen this before)
'i'm to intercede' is the wordplay.
'to intercede' becomes 'mediate' ('mediate' can be a synonym of 'intercede').
'im'+'mediate'='IMMEDIATE'
(Other definitions for immediate that I've seen before include "Present" , "Involving no delay" , "Prompt,straightaway" , "Most urgent; current" , "Instantaneous" .)